a) We presume "roll a 5" means rolling the dice so they come up with a total of 5 spots on top. 5 is not an even number, so when 5 is showing, the numbers on the two dice must be different, hence cannot be doubles.
b) Since these events are mutually exclusive, we can simply add their probabilities: (1/9) +(1/6) = 2/18 +3/18 = 5/18.