I've attached a plot of one such cross section (grayish orange) with its diameter lying in the region (blue) bounded above by the curve [tex]y=e^{-x}[/tex] (red). (This cross section is taken at [tex]x=0.25[/tex].)
The area of each cross section in terms of its diameter [tex]d[/tex] is [tex]\dfrac{\pi\left(\frac d2\right)^2}2=\dfrac{\pi d^2}8[/tex], where the diameter is determined by the vertical distance (in the x-y plane) between the curve [tex]y=e^{-x}[/tex] and the x-axis [tex]y=0[/tex]. So, [tex]d=e^{-x}[/tex].
The volume would then be
[tex]\displaystyle\int_0^1\frac{\pi(e^{-x})^2}8\,\mathrm dx=\frac\pi8\int_0^1e^{-2x}\,\mathrm dx=\frac{\pi(e^2-1)}{16e^2}[/tex]