in the sn1 mechanism conditions, silver nitrate is added. in principle, the nitrate anion can act as a nucleophile, but is so poor of a nucleophile that any chemical reactivity from it is negligible. knowing that, what is the nucleophile in the sn1 reaction in the reactions using silver nitrate if it is not the nitrate ion?

Respuesta :

Nitrate performs an crucial function withinside the technique as nicely with the aid of using performing as a nucleophile that promotes a thermodynamic self-correcting technique.

the response of an alkyl chloride with silver nitrate (AgN03) to shape silver chloride and an alkyl nitrate, the silver atom coordinates with the chloride facilitating the formation of the carbocation. Nitrate ion is one of these susceptible nucleophile, that direct SN2 displacement can't occur.

The nitrate is a terrible nucleophile. It has three oxygen atoms pulling electron density far from the nitrogen, and there may be additionally a truthful quantity of resonance that lowers the nucleophilicity notably as well SN1 response mechanism follows a step-with the aid of using-step technique in which first, the carbocation is shaped from the elimination of the leaving group.

Then the carbocation is attacked with the aid of using the nucleophile. Finally, the deprotonation of the protonated nucleophile takes location to present the specified product.

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