In order to calculate the angle, we can use the formula below for a constructive interference (the interference is constructive because the fringe is bright):
[tex]d\sin\theta=m\lambda[/tex]Where d is the distance between the slits, m is the order of the interference and lambda is the wavelength.
So, using d = 8.25 * 10^-5, m = 2 and lambda = 4.5 * 10^-7, we have:
[tex]\begin{gathered} 8.25\cdot10^{-5}\cdot\sin\theta=2\cdot4.5\cdot10^{-7}\\ \\ \sin\theta=\frac{9\cdot10^{-7}}{8.25\cdot10^{-5}}\\ \\ \sin\theta=1.091\cdot10^{-2}\\ \\ \theta=0.625° \end{gathered}[/tex]Therefore the correct option is the second one.