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It is the first one.

The chemical reaction used to identify a mineral is the first diagram that is finding the chemical reaction with the acid.

A mineral can be identified using acid:

The chemical reaction of the mineral with the acid can be used for the identification of the mineral. An acid test is the easiest way. When an acid is dropped on carbonated minerals, it will show reactions. It will release carbon dioxide into the air.

Thus, the first diagram shows the chemical reaction used to identify a mineral.

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