Use Moseley's Law for Kalpha.
nu = (2.47 x 10^15) (Z - 1)^2
We know that E = h*nu, so...
nu = E / h
substitute, rearrange, etc, you get...
Z = sqrt( (E/h)/(2.47*10^15) ) + 1
Answer yields 18.98 ... ~ 19, hence Potassium, like I wrote earlier in reference to NIST tables.