propose a reasonable synthesis to get benzylamine from toluene

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02-05-2018
Chemistry

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propose a reasonable synthesis to get benzylamine from toluene

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transitionstate transitionstate · Answer 1 · 2018-05-12T11:11:18+02:00

Benzyl Amine is synthesized from Toluene in two steps;

Step 1: Bromination of Methyl Group in Toluene:
Bromination is carried out on methyl group present on Benzene ring through free radical mechanism by treating toluene with N-Bromosuccinimide (NBS) and Benzyl Bromide is formed.

Step 2: Benzyl Bromide into Benzyl Amine;
This step is carried out utilizing a neme reaction "Gabriel Reaction". Benzyl bromide is treated with Potassium Phthalamide and an intermediate is formed which on treatment with Hydrazine produces Benzyl amine.