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According to Arrhenius Theory of acids and bases, an Arrhenius acid produces H+ when dissolved in water.

Among the four options, (1) H2SO4 is the correct one because when it dissolves in water, it liberates H+.

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Answer: Option (1) is the correct answer.

Explanation:

An Arrhenius acid is defined as the acid which dissociates in water to give hydrogen or [tex]H^{+}[/tex] ions.

For example, [tex]H_{2}SO_{4} \rightarrow 2H^{+} + SO^{2-}_{4}[/tex]

So, [tex]H_{2}SO_{4}[/tex] is an Arrhenius acid as it is giving hydrogen ions upon dissociation.

Whereas a compound which dissociates in water to give hydroxide or [tex]OH^{-}[/tex] ions is known as Arrhenius base.

For example, [tex]NaOH \rightarrow Na^{+} + OH^{-}[/tex]

So, NaOH is an Arrhenius base as it gives hydroxide ions upon dissociation.

Thus, we can conclude that out of the given options the compound [tex]H_{2}SO_{4}[/tex] is an Arrhenius acid.

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