He bought 2 20-cent stamps.
That is $0.40.
He spent $4.60 on the other stamps.
He bought x 6-cent stamps, y 10-cent stamps, and z 8-cent stamps.
y + 10 = x
z = 3y
6x + 10y + 8z = 460
6(y + 10) + 10y + 8(3y) = 460
6y + 60 + 10y + 24y = 460
40y + 60 = 460
40y = 400
y = 10
x = y + 10 = 10 + 10 = 20
z = 3y = 3(10) = 30
He bought
20 6-cent stamps
10 10-cent stamps
30 8-cent stamps
2 20-cent stamps