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A right is something you are or should be guaranteed as a human. Examples: Life, liberty, and the pursuit of happiness. A privilege is something you are not entitled to, and are lucky to have. Example: Free education. More generally, an advantage that many other people may not have.
A right is something you are entitled to no matter the situation, for example a lawyer when being accused of something, whether they have evidence or not you have the right to defend yourself. Contrasting, a privilege is immunity granted to a person or group of people. A privileged person doesn't have to worry about being a certain race and being paid less. Another example of privilege is, men on average are paid more then women, even while having the same career, degree and experience. A right against this would be workplace equality, while not always given it is a right and can be fought for.
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