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The adverb that modifies the verb is instantly. Adverbs usually end in ly, so that should already be a clue, but the main reason is because the question is how fast did the scientists know? They knew instantly. 

Answer:

The adverb that modifies a verb is instantly.

Explanation:

An adverb is a word that describes where, when, or, in this case, how an action took place. In this sentence, the adverb is modifying a verb, because it is making clear how they scientists knew, but an adverb could also serve as modifier of an adjective or another adverb.

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