To solve this problem we use the z test. The formula for z score is:
z = (x – u) / s
where,
x = sample value = 13 and below
u = mean value = 27
s = standard deviation = 14
z = (13 – 27) / 14 = -1
using the z table to get the standard normal probabilities, the p value at z = -1 is:
P = 0.1587
This means that 15.87% that the discharge is 13 mg/L and below.