Respuesta :
The ground state electron configuration of carbon is 1s22s22p2. An excited state electron configuration of carbon is 1s22s12p3. This is the state of carbon when it undergoes chemical bonding to form four covalent bonds, as in methane, CH4. However, the experimental evidence shows that all four bonds have the same energy, which can only be explained by the concept that the 2s and 2p orbitals hybridize to form four sp3 orbitals, each with one unpaired electron.
The selection rules for quantum numbers allow finding the base state electron configuration of carbon is:
- Base state configuration 1s² 2s²2p²
- The excited state configuration of the sub-level 2s and the three sub-levels 2p forms a hybrid orbital called sp³ where the four orbitals have the same energy.
Atoms have an electronic configuration given by the rules of selection of quantum numbers:
- Principal. It is the fundamental number (n) and has values from 1 to infinity, it represents the periods of the periodic table.
- Secondary or orbital. It is the second number and its symbol is l and it has values from zero to n-1, in general it is written in the form of the letter: s p d f.
- Magnetic. The orbital motion of electrons is given and can have values from -l to l.
There is a fourth quantum number when it is the spin and it can only have two values +1/2 and - ½
Carbon has an atomic number 6, therefore its configuration of the ground state is:
1s² 2s² 2p²
When the atom is excited, an electron jumps from the 2 s² level to the 2p² level, leaving the configuration
2s¹ 3p³
In this configuration it has four unpaired electrons, therefore I could form four chemical bonds, experiential measurements show that these four bonds have the same energy, for this to happen there must be a hybridization between the s and p levels where it forms the sp³ orbitals that have the same Energy.
In conclusion using the selection rules of quantum numbers we can find the base state electron configuration of carbon:
- Base state configuration 1s² 2s²2p²
- The excited state configuration of the sub-level 2s and the three sub-levels 2p forms a hybrid orbital called sp³ where the four orbitals have the same energy.
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