First find a common denominator so you can compare them easier. I chose 12. Multiply the numerator and denominator by the number that makes the denominator 12. 2/3 is multiplied by 4 and 2/4 is multiplied by 3. You are left with 8/12 and 6/12. 8/12 is bigger so it looks like
8/12>6/12
Hope this helps!