acetyl coa carboxylase generates malonyl-coa from acetyl-coa co2. in the biosynthesis of palmitate, what is the fate of the carbon atom in the co2 that was incorporated into malonyl-coa?

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queenjade1663 queenjade1663

01-12-2022
Chemistry

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acetyl coa carboxylase generates malonyl-coa from acetyl-coa co2. in the biosynthesis of palmitate, what is the fate of the carbon atom in the co2 that was incorporated into malonyl-coa?

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SancharyBhattacharya SancharyBhattacharya · Answer 1 · 2022-12-05T20:38:33+01:00

A 3-carbon dicarboxylic acid called malonate is linked to Coenzyme A in malonyl CoA. Using the biotin cofactor of the enzyme acetyl-CoA carboxylase, malonate is created from acetyl-CoA by adding CO₂ .

What is the source of malonyl-CoA?

Acetyl-CoA carboxylase (Acc1p) produces malonyl-CoA, which is produced as the first and only step in the production of fatty acids. The activity of Acc1p is closely controlled both transcriptionally and post-translationally, and Snf1p protein kinase phosphorylation of Acc1p inhibits its activity.

Is malonyl-CoA an extender or starter?

All forms of PKSs use malonyl-CoA as an extender unit. Malonyl-CoA is always incorporated into the developing polyketide through a decarboxylative Claisen condensation between the carboxyl group of a thioester and the enolate ion produced by malonyl-decarboxylation. CoA's .

Is CO2 used in fatty acid synthesis?

Although CO2 or HCO3 are not absorbed into the fatty acids, the need for carbon dioxide as a bicarbonate ion is a crucial component in the production of fatty acids. This indicates a method where CO2 is initially given to a precursor, serving its role, and then eventually withdrawn.

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