alpha polonium crystallizes in a simple cubic unit cell with an edge length of 336 pm, the density becomes 7.318 g/cm³.
The smallest repeating unit with complete crystal structural symmetry is designated as a unit cell. The unit cell geometry, sometimes referred to as a parallelepiped, provides six lattice parameters, which are the lengths of the cell edges (a, b, and c) and the angles at which they are spaced apart ( α,β,γ ).
Given that,
alpha polonium crystallizes in a simple cubic unit cell with an edge length (a) of 336 pm.
As we know, the relation between radius (r) and edge length (a) for simple cubic unit cell is: 2 r = a
Thus, r = a/2
r = 336/2 [ given a = 336 pm]
r = 168 pm
Now, density (d) = (Z × M) / a³ × [tex]N_A[/tex]
Here, Z = number of atom in a simple cubic unit cell = 1
M = molecular weight of polonium
[tex]N_A[/tex] = Avogadro's no.
d = ( 1 × 209) / (168 ×10⁻¹²)³ × (6.023 × 10²³)
d = 7.318 × 10⁷ g/m³
d = 7.318 g/cm³
So, the density of alpha polonium is 7.318 g/cm³.
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