The key difference between voltaic and electrolytic cells is that in a voltaic cell, the flow of electrons is the result of a spontaneous redox reaction, whereas in an electrolytic cell, electrons are pushed by an outside power source, such as a battery.
In an electrolytic cell, The creation of electrical energy in this instance is caused by a spontaneous redox reaction. Electrical energy must be provided to start the redox reaction since it is not spontaneous. An external voltage in an electrolytic cell causes a current to flow through the cell, which in turn triggers a chemical reaction that is not spontaneous. The development of a spontaneous chemical reaction in a galvanic cell results in the passage of an electric current.
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