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In the winter in the northern hemisphere, the concentration of carbon dioxide in the atmosphere increases because this area has mostly ocean and less plants.

After water vapor, carbon dioxide is one of the most abundant greenhouse gas in the Earth's atmosphere. A greenhouse gas is a gas that traps heat from the Sun and then radiates it back toward the planet's surface, rather than the heat being reflected back into space.

The majority of the Earth's landmass, and hence plant life, is located in the Northern Hemisphere. So, during summer in the Northern Hemisphere, when plants are more active and uptake more carbon dioxide for photosynthesis, atmospheric carbon dioxide levels generally  drop. On the other hand, during the Northern Hemisphere's winter, atmospheric carbon dioxide levels rise because the decomposing plant matter in the Northern Hemisphere releases carbon dioxide, and there is not enough photosynthesizing plant life in the Southern Hemisphere (which is experiencing summer during the Northern Hemisphere's winter) to counter this effect.

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