ATP is a source of energy is that the products of hydrolysis of ATP have less free energy than the reactants because :
Due to the high-energy phosphate bonds in ATP molecules, a significant amount of free energy is released during hydrolysis. The initial hydrolysis of ATP takes place at the gamma phosphate and results in the production of adenosine diphosphate (ADP) and a free phosphate group.
7.3 kcal/mol of energy is released during the hydrolysis of one ATP molecule (G = 7.3 kcal/mol of energy).
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