Physical change: a new substance is not produced.
Chemical change: produces a new substance.
The substance x has one white dot, two black dots and one white again.
W - B - B - W.
If we look at the change 1 we can see that we have one green, two black and another green.
Is it possible to have one green atom? What does that mean? It means that we have another atom there. The problem says that the sample is in a sealed box, so that no matter can enter or leave. So in my opinion the first one is impossible.
In the second change I can't decide between physical and chemical. I think it is a chemical change because there is a rearrengement.
In the third change there are 12 molecules, Each molecule has two black atoms and 4 white atoms. In the substance x only had 24 white atoms, but in the change 3 we have 48 white atoms. As we said before the sample is in a sealed box, so that no matter can enter or leave. So it also impossible.