Answer
[tex]adding\text{ }Cu\left(NH_3\right)_4^{2+}(aq)\text{ }ion[/tex]
Explanation
The given equation is
[tex]Cu\left(H₂O\right)_4^{2+}(aq)+4NH_3(aq)\rightarrow Cu(NH_3)_4)^{2+}(aq)+4H_2O(aq)[/tex]
From the information provided, the species/reactant responsible for the pale sky-blue color on the left side of the reaction is the coordination compound
[tex]Cu\left(H₂O\right)_4^{2+}(aq)[/tex]
And the species/reactant responsible for the dark blue color on the right side of the reaction is the coordination compound
[tex]Cu\left(NH_3\right)_4^{2+}(aq)[/tex]
Therefore a change to a solution at equilibrium that will make the solution darker is
[tex]adding\text{ }Cu\left(NH_3\right)_4^{2+}(aq)\text{ }ion[/tex]