To solve this problem we have to use Avogadros number that states that a mole of any element or compound has 6.022e23 atoms or molecules.
The first step is to determine how many moles are there in 3.00e21 atoms of arsenic:
[tex]3.00\times10^{21}atoms\cdot\frac{1mol}{6.022\times10^{23}atoms}=4.98\times10^{-3}mol[/tex]Now, use the molecular weight to determine the mass of the obtained number of moles:
[tex]4.98\times10^{-3}mol\cdot\frac{74.92g}{1mol}=0.37g[/tex]The mass is 0.37g of arsenic.