a) The first step is finding the molar mass of CH4 to convert the mass given (2.2 g) into moles.
MM = 12.0 + 4*1.0 = 16 g/mol
If 16 g = 1 mole, we can calculate how many moles are 2.2 g by doing the following:
16 g ---- 1 mole
2.2 g ----- x mole
[tex]\frac{16}{2.2}=\frac{1}{x}\Rightarrow16x=2.2\Rightarrow x=0.1375\text{ }mol[/tex]Now we use Avogadro's number to find how many molecules are present in this amount of moles of methane (CH4).
Avogadro's number is 6.0*10^23 molecules/mol
1 mole ---- 6.0*10^23 molecules
0.1375 mole ---- y molecules
[tex]\frac{1}{0.1375}=\frac{6.0*10^{23}}{y}\Rightarrow y=0.1375*6.0*10^{23}\text{ }\Rightarrow y=8.3*10^{22}\text{ molecules}[/tex]There are 8.3*10^22 molecules in 2.2 g of CH4.