CO(g) + 2 H2 --> CH3OH2.50 g of hydrogen is reacted with 30.0 L of carbon monoxide at STP. What is the volume of excess remaining in liters?

Respuesta :

The first step to solve this question is to convert the mass of H2 to moles, using its molecular mass:

[tex]2.50gH_2\cdot\frac{molH_2}{2.00gH_2}=1.25molH_2[/tex]

Now, convert the volume of CO to moles using the ideal gas law:

[tex]PV=nRT[/tex]

Solve the equation for n and replace P, V, T and R for its known values (1atm, 30.0L, 0.082atmL/molK and 273.15K):

[tex]\begin{gathered} n=\frac{PV}{RT} \\ n=\frac{1atm\cdot30.0L}{0.082atmL/molK\cdot273.15K} \\ n=1.34mol \end{gathered}[/tex]

From the given equation we can find how many moles of CO react with 1.25 moles of H2:

[tex]1.25molH_2\cdot\frac{1molCO}{2molH_2}=0.625molCO[/tex]

Substract this amount to the value of n to find the excess remaining:

[tex]1.34molCO-0.625molCO=0.715molCO[/tex]

Use the ideal gas law once again, but this time to find the volume occupied by 0.715moles of CO:

[tex]\begin{gathered} V=\frac{nRT}{P} \\ V=\frac{0.715mol\cdot0.082atmL/molK\cdot273.15K}{1atm} \\ V=16.01L \end{gathered}[/tex]

It means that 16.01L of CO are remaining.

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