To balance the given equation using algebraic method, assign variables to the coefficients of each substance, for example, in this case:
[tex]a\cdot KNO_3+b\cdot H_2CO_3\to c\cdot K_2CO_3+d\cdot HNO_3[/tex]The coefficient of KNO3 is a, for H2CO3 is b, for K2CO3 is c and for HNO3 is d.
Now, make an element balance per each element present in the reaction. For example, for potassium, in the reactants it is present a times, in the products it is present 2c (coefficient times subscript), it means that:
[tex]a=2c[/tex]For oxygen, in the reactants it is present 3a+3b times, in the products it is present 3c+3d times:
[tex]3a+3b=3c+3d[/tex]For nitrogen:
[tex]a=d[/tex]For hydrogen:
[tex]2b=d[/tex]For carbon:
[tex]b=c[/tex]Now, the statement tells us to use 2 as the value of a. Using this value and the algebraic equations stated, we can find the b, c and d:
[tex]\begin{gathered} a=2c \\ 2c=a \\ c=\frac{a}{2} \\ c=\frac{2}{2} \\ c=1 \end{gathered}[/tex][tex]\begin{gathered} b=c \\ b=1 \end{gathered}[/tex][tex]\begin{gathered} a=d \\ d=a \\ d=2 \end{gathered}[/tex]Now, that we have the values for a, b, c and d, we can replace them in the chemical equation to obtain the balanced equation:
[tex]2KNO_3+H_2CO_3\to K_2CO_3+2HNO_3[/tex]