Valence Electron Theory : According to the valence bond theory, Electrons in a molecule be the tenant of atomic orbitals rather than molecular orbitals. The overlapping of atomic orbitals bring about in the emergence of a chemical bond and the electrons are restrained in the bond region because of overlapping.
According to question,
According to valence electrons theory,
So, the two chlorine atoms parts one electron each to form a chlorine molecule. Thus, a single covalent bond is set up in the middle of two chlorine atoms. The bond in is the conclusion of the overlap of two 3p orbitals from two Cl atoms.
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