An electron is stimulated from the ground state to a higher energy level as a result of the absorption of a photon in the PAR range by a photosynthetic pigment.
These excited states can go from one pigment molecule to another, but because moving from carotenoids and chlorophyll b to chl an is energetically less favourable, excited states created on those pigment molecules end up on chl a.
The functional components of photosynthesis are called photosystems, and they are identified by specific pigment organisation and association patterns.
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