In a mass of air in which no water is being added or removed, a temperature increase will decrease relative humidity. The relative humidity will drop when a system's temperature rises because pressure will rise while stays constant. Similar to this, as a system's temperature drops, the relative humidity rises because drops while p remains constant.
The relative humidity falls as the temperature rises while the water vapor content remains constant. The reason for this is that colder air can become saturated with less moisture than warmer air. They both use energy to chill the space and lower the interior humidity and temperature.
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