The larger, higher molecular weight molecule would have a higher melting point because of greater dispersion forces present.
A hydrocarbon is a compound that contains carbon and hydrogen. Since hydrocarbons are nonpolar molecules, the only kind of intermolecular forces present are the dispersion forces.
Hence, when comparing 2 hydrocarbons, the larger, higher molecular weight molecule would have a higher melting point because of greater dispersion forces present.
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