The amount of heat released by the sample has been 22.54 kJ. Thus, option C is correct.
The specific heat has been defined as the amount of heat required to raise the temperature of 1 gram of substance by 1 degree Celsius.
The specific heat has been expressed as:
[tex]q=mc\Delta T[/tex]
The iron and calorimeter are in side the closed system. Thus, the energy released by the sample, has been equivalent to the energy absorbed by the calorimeter.
[tex]q_{released}=q_{absorbed}\\ q_{released}=m_{calorimeter}\;c_{calorimeter}\;\Delta T[/tex]
The given mass of calorimeter has been, [tex]m_{calorimeter}=1350\;\rm g[/tex]
The specific heat of the calorimeter has been, [tex]c_{calorimeter}=5.82\;\rm J/g^\circ C[/tex]
The change in temperature of the calorimeter has been, [tex]\Delta T=2.87^\circ \rm C[/tex]
Substituting the values for heat released:
[tex]q_{released}= 1350\;\text g\;\times\;5.82\;\text J/\text g^\circ \text C\;\times\;2.87^\circ \text C\\ q_{released}=22,549.5\;\text J\\ q_{released}}=22.54\;\rm kJ[/tex]
The amount of heat released by the sample has been 22.54 kJ. Thus, option C is correct.
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