A student weighs out a sample of 9.4 mg of an unknown metal. The sample of metal reacts with hydrochloric acid at a pressure of 1 atm and 25.0˚C to form 9.51 mL of hydrogen gas. Assuming the unknown metal has a +2 oxidation state, what is the identity of the metal?

Respuesta :

The identity of the metal is Magnesium, Mg

Let the unknown metal be M

  • Next, we shall determine the number of mole of H₂ produced from the reaction.

Pressure (P) = 1 atm

Temperature (T) = 25 °C = 25 + 273 = 298 K

Volume (V) = 9.51 mL = 9.51 / 1000 = 0.00951 L

Gas constant (R) = 0.0821 atm.L /Kmol

Number of mole (n) =?

PV = nRT

1 × 0.00951 = n × 0.0821 × 298

0.00951 = n × 24.4658

Divide both side by 24.4658

n = 0.00951 / 24.4658

n = 3.89×10¯⁴ mole

  • Next, we shall determine the mole of the metal needed to produce 3.89×10¯⁴ mole of H₂.

M + 2HCl —> MCl₂ + H₂

From the balanced equation above,

1 mole of M reacted to produce 1 mole of H₂.

Therefore,

3.89×10¯⁴ mole of M will also react to 3.89×10¯⁴ mole of H₂.

  • Finally, we shall determine the identity of the metal, M.

Mass of metal = 9.4 mg = 9.4×10¯³ g

Mole of metal = 3.89×10¯⁴

Molar mass of metal =?

Molar mass = mass / mole

Molar mass of metal = 9.4×10¯³ / 3.89×10¯⁴

Molar mass of metal = 24.2 g/mol

Comparing the molar mass of the metal with those in the periodic table, the identity of the metal is Magnesium, Mg

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