Using the equations 2 sr(s) + o₂ (g) → 2 sro (s) ∆h° = -1184 kj/mol co₂ (g) → c (s) + o₂ (g) ∆h° = 394 kj/mol determine the molar enthalpy (in kj/mol) for the reaction c(s) + 2 sro(s) → co₂ (g) + 2 sr(s).

Respuesta :

Considering the Hess's Law, the enthalpy change for the reaction is 790 kJ/mol.

Hess's Law indicates that the enthalpy change in a chemical reaction is the sum of the ∆H of each stage of the reaction will give us a value equal to the ∆H of the reaction when it occurs in a single stage.

In this case you want to calculate the enthalpy change of:

C(s) + 2 SrO(s) → CO₂ (g) + 2 Sr(s)

You know the following reactions, with their corresponding enthalpies:

Equation 1: 2 Sr (s) + O₂ (g) → 2 SrO (s) ∆H° = -1184 kJ/mol

Equation 2: CO₂ (g) → C (s) + O₂ (g) ∆H° = 394 kJ/mol  

  • First step

In this case, first, to obtain the enthalpy of the desired chemical reaction you need 1 mole of C (s) on reactant side and it is present in second equation. But since this equation has 1 mole of C (s) on the product side, it is necessary to locate this on the reactant side (invert the reaction). And when an equation is inverted, the sign of ΔH also changes.  

  • Second step

Now, 2 moles of SrO (s) must be a reactant and is present in the first equation. Since this equation has 2 moles of Sr0 (s) on the product side, it is necessary to locate the O on the reactant side (invert the reaction) and the sign of ΔH changes.

  • Summary

In summary, you know that two equations with their corresponding enthalpies are:

Equation 1:  2 SrO (s) → 2 Sr (s) + O₂ (g)     ∆H° = 1184 kJ/mol

Equation 2: C (s) + O₂ (g) → CO₂ (g)     ∆H° = -394 kJ/mol

Adding or canceling the reactants and products as appropriate, and adding the enthalpies algebraically, you obtain:

C(s) + 2 SrO(s) → CO₂ (g) + 2 Sr(s)     ΔH= 790 kJ/mol

Finally, the enthalpy change for the reaction is 790 kJ/mol.

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