Calcium will be more reactive .
Lets look at EC of Calcium
[tex]\\ \sf\longmapsto 1s^22s^22p^63s^23p^64s^2[/tex]
It will react with water like below
[tex]\\ \sf\longmapsto Ca+H_2O=Ca(OH)_2[/tex]
Now
Looking at EC of potassium
[tex]\\ \sf\longmapsto 1s^22s^22p^63s^23p^64s^1[/tex]
It will react with water like below
[tex]\\ \sf\longmapsto K+H_2O=KOH[/tex]