The statement that best describes Romeo's relationship with Rosaline when the audience first meets him is that she doesn't return his affections, but he can't stop thinking about her.
When Romeo describes his relationship with Rosaline with the audience, he talks about her being beautiful, to which he has never seen her match since the world begun, but unfortunately, she does not return his love as she wants to remain chaste. He is sad and depressed as a result.
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