The reaction that can be used to extract copper metal from copper sulfate solution would be equation 2.
Fe will displace Cu from CuSO4 because it is more reactive. In other words, Fe ranks higher than Cu in the reactivity series.
Thus: [tex]Fe + CuSO_4 ---> Cu + FeSO_4[/tex]
Even though Na will displace Cu from CuSO4, equation 1 will result in the formation of Cu(OH)2 instead of free Cu because it is a double replacement reaction.
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