Question

When two volatile liquids (X and Y) are mixed, the solution process involves
1. breaking the intermolecular X---X and Y---Y attractions, and
2. forming new X---Y attractions.

Complete this table describing how the relative strengths of these attractive forces affect vapor pressure and enthalpy of solution. (see attachment)

Answer 1

STRENGTHS                                         Raoult's law deviations     DeltaHsoln

1. X---X, Y---Y, and X---Y are equal            Zero                                Zero
2. X---Y is strongest                                   Negative                         Negative
3. X---Y is weakest                                     Positive                           Positive

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