We use the concept on colligative properties to calculate the number of moles in the system above. We calculate as follows:
ΔT = -kf(m)
where ΔT is the change in freezing point, kf is the freezing point depression and m is the molality of the solution.
-10 = -1.86(m)
m = 5.37 mol/kg
number of moles = 5.37 (4.50) = 24.19 moles of methanol