Question

Explain why anhydrous aluminium chloride is fairly soluble in organic solvent while anhydrous magnesium chloride is insoluble​

Answer 1

Aluminium chloride is covalent hence soluble in organic solvent while magnesium chloride being ionic is insoluble in organic solvent

Answer 2

• AlCl3 takes electrons from other atoms very ease in an effort to complete its valence shell, which consists of eight electrons.
• Because of this, it typically acts like a Lewis acid.
• The Al atom accepts a single pair of electrons from a Cl atom in the reaction shown below.

• Aluminium chloride is covalent hence soluble in organic solvent while magnesium chloride being ionic is insoluble in organic solvent.
• AlCl3 is  soluble in organic solvents , freely soluble in many organic solvents, such as benzophenone, nitrobenzene.

Is AlCl3 soluble or insoluble?

• AlCl3 is soluble in water.
• The reaction between AlCl3 and water is exothermic and aggressive.

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