Applying 1st law of thermodynamics:
Q = Delta U + WB
WB is the workdone by the system
WB = 346 J
As,
Delta U = ( m ) ( CV ) ( T2 - T1 )
CV = ( Delta U ) / ( m ) ( T2 - T1 )
Putting the values in equation:
CV = ( 8485 J ) / ( 80.0 g ) ( 225 C - 25 C )
CV = 0.5303 J / g - C degree
Now putting in original equation:
Q = Delta U + WB
Q = ( 8485 ) + ( 346 ) = 8831 J
8831J is the specific heat of the gas