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A vessel of capacity 400 cc filled with chlorine under 80 cm is connected by a narrow tube and stopcock with another vessel of capacity 250 cc filled with nitrogen under 100 cm. what will be the pressure when the stopcock is opened?

Respuesta :

Answer:

The pressure when the stopcock is opened is opened is 87.783 cm

Explanation:

The given parameters of the question are;

The volume of the vessel of chlorine = 400 cc

The pressure of the vessel of chlorine = 80 cm

The volume of the vessel of chlorine = 250 cc

The pressure of the vessel of chlorine = 100 cm

Daltons law of Partial Pressures states that the total pressure exerted by a volume of a mixture of gases is equal to the partial pressures exerted by the individual gases in the mixture with respect to the given volume

Therefore;

The total volume of the mixture = 400 cc + 250 cc = 650 cc

The partial pressure exerted by the chlorine gas in the total volume is given by Boyles law as follows;

P₁·V₁ = P₂·V₂

P₂ = P₁·V₁/V₂

Where;

P₁ = 80 cm = The pressure in volume V₁ = 400 cc

P₂ₓ = The partial pressure of chlorine in volume V₂ = 650 cc

Substituting, we have;

P₂ₓ = 80 × 400/650 ≈ 49.321 cm

Similarly, the partial pressure exerted by the nitrogen gas in the total volume is given by Boyles Law as follows;

P₂ₐ = P₁·V₁/V₂

Where;

P₁ = 100 cm = The pressure in volume V₁ = 250 cc

P₂ₐ = The partial pressure of nitrogen in volume V₂ = 650 cc

Substituting, we have;

P₂ₐ = 100× 250/650 ≈ 38.462 cm

The pressure of the combined gas, P, when the stopcock is opened is opened is given by Dalstons Law of partial pressure as P = P₂ₐ + P₂ₓ

Therefore, the pressure, P when the stopcock is opened is opened = 49.321 cm + 38.462 cm = 87.783 cm

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