Based on the bond energies for the reaction below, what is the enthalpy of the reaction?HC≡CH (g) + 5/2 O₂ (g) → 2 CO₂ (g) + H₂O (g)

Respuesta :

Answer:

1219.5 kj/mol

Explanation:

To reach this result, you must use the formula:

ΔHºrxn = Σn * (BE reactant) - Σn * (BE product)

ΔHºrxn = [1 * (BE C = C) + 2 * (BE C-H) + 5/2 * (BE O = O)] - [4 * (BE C = O) + 2 * (BE O-H).

The BE values are:

BE C = C: 839 kj / mol

BE C-H: 413 Kj / mol

BE O = O: 495 kj / mol

BE C = O = 799 Kj / mol

BE O-H = 463 kj / mol

Now you must replace the values in the above equation, the result of which will be:

ΔHºrxn = [1 * 839 + 2 * (413) + 5/2 * (495)] - [4 * (799) + 2 * (463) = 1219.5 kj/mol

Based on the bond energies, the reaction

HC≡CH(g) + 5/2 O₂(g) → 2 CO₂(g) + H₂O(g) has a standard enthalpy of reaction of - 1222 kJ/mol.

The given reaction is:

HC≡CH(g) + 5/2 O₂(g) → 2 CO₂(g) + H₂O(g)

The bond energies (E) of the reactions can help to calculate the standard enthalpy of the reaction (ΔH°rxn) using the following expression.

[tex]\triangle H_ \degrees {rxn} = \sum E_{reactants} - \sum E_{products}[/tex]  

The broken bonds are:  

  • HC≡CH  
  1. 1 triple C-C bond
  2. 2 single C-H bonds
  •  O₂
  1.  5/2 double O-O bonds

The formed bonds are:  

  •  CO₂  
  1. 4 double C-O bonds
  • H₂O  
  1. 2 single O-H bonds

Solution:

bond energies in the formula:

[tex]\triangle H_ \degrees {rxn} = 835+ 2(411) + 2.5(494) - 4(799) - 2(459)[/tex]

= 1222 kJ/mol  

Thus, Based on the bond energies, the reaction:

HC≡CH(g) + 5/2 O₂(g) → 2 CO₂(g) + H₂O(g) has a standard enthalpy of reaction of -1222 kJ/mol.  

Learn more: brainly.com/question/24857760

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