Answer:
The structures are attached in file.
Hydrogen bonding and intermolecular forces is the reason for ranks allotted.
Explanation:
In determining Lewis structure, we calculate the overall number of valence electrons available for bonding. Â Making carbon (the least electronegative atom) the central atom in the structure, we allocate valence electrons until each atom has achieved stability.
In order of decreasing affinity to water molecules:
[tex]CO_{3}^{2-} > HCO_{3} ^{2-} > H_{2} CO_{3}[/tex]
This is due to the fact that the [tex]CO_{3}^{2-}[/tex]will accept protons more readily than the bicarbonate ion, [tex]HCO_{3} ^{2-}[/tex]. Carbonic acid, [tex]H_{2} CO_{3}[/tex] will not accept any more protons, hence it is the least attractive to water molecule, even though soluble.