If the equilibrium constant for the reaction 3I- (aq) + S2O82- (aq)  I3- (aq) + 2SO42- (aq) is K, what is the equilibrium constant for the reaction (1/3)I3- (aq) + (2/3)SO42- (aq)  I- (aq) + (1/3)S2O82- (aq) ?

Respuesta :

Answer: The value of equilibrium constant for Equation 2 is [tex]K'=\sqrt[3]{\frac{1}{K}}[/tex]

Explanation:

The chemical equation whose equilibrium constant is given follows:

[tex]3I^-(aq.)+S_2O_8^{2-}(aq.)\xrightarrow{K} I_3^-(aq.)+2SO_4^{2-}(aq.)[/tex]     ......(1)

The chemical equation whose equilibrium constant is to be calculated follows:

[tex]\frac{1}{3}I_3^-(aq.)+\frac{2}{3}SO_4^{2-}(aq.)\xrightarrow {K'} I^-(aq.)+\frac{1}{3}S_2O_8^{2-}(aq.)[/tex]       .........(2)

As, the Equation 2 is the result of the reverse of one-third of Equation 1. So, the equilibrium constant for the Equation 2 will be the cube root of inverse of equilibrium constant of Equation 1.

The value of equilibrium constant for Equation 2 is:

[tex]K'=\sqrt[3]{\frac{1}{K}}[/tex]

Hence, the value of equilibrium constant for Equation 2 is [tex]K'=\sqrt[3]{\frac{1}{K}}[/tex]

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