Answer : The initial volume was, 71.2 mL
Explanation :
To calculate the volume when temperature and pressure has changed, we use the equation given by combined gas law.
The equation follows:
[tex]\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}[/tex]
where,
[tex]P_1,V_1\text{ and }T_1[/tex] are the initial pressure, volume and temperature of the gas
[tex]P_2,V_2\text{ and }T_2[/tex] are the final pressure, volume and temperature of the gas
We are given:
[tex]P_1=0.85atm\\V_1=?\\T_1=66^oC=[66+273]K=339K\\P_2=0.60atm\\V_2=94mL\\T_2=43^oC=[43+273]K=316K[/tex]
Now put all the given values in above equation, we get:
[tex]\frac{0.85atm\times V_1}{339K}=\frac{0.60atm\times 94mL}{316K}[/tex]
[tex]V_1=71.2mL[/tex]
Therefore, the initial volume was, 71.2 mL