What concentration of SO 2 − 3 SO32− is in equilibrium with Ag 2 SO 3 ( s ) Ag2SO3(s) and 7.10 × 10 − 3 7.10×10−3 M Ag + Ag+?

Respuesta :

The question happens to be in an incorrect order but the correct question can be seen below;

What concentration of [tex]SO^{2-}_3[/tex] is in equilibrium with [tex]Ag_2SO_{3(S)}[/tex] and [tex]7.10*10^{-3}M[/tex] [tex]Ag^+[/tex]? (The [tex]K_{sp}[/tex] of  

Answer:

[tex]2.96*10^{-10}M[/tex]

Explanation:

The concentration of [tex]SO^{2-}_3[/tex]  can be determined by using the solubility concept.

Given ionic solid is [tex]Ag_2SO_{3(S)}[/tex] ;

The Equilibrium Equation for the ionic compound will be:

[tex]Ag_2SO_{3(S)}[/tex] ⇄[tex]2Ag_{(aq)}[/tex] + [tex]SO^{2-}_3_{(aq)}[/tex]

Now, the solubility product  ([tex]K_{sp}[/tex]) of the ionic compound will be;

[tex]K_{sp}[/tex] [tex]= [Ag^+]^{2}[SO^{2-}_3][/tex]

Given that;

the concentration [tex]Ag^+[/tex] is [tex]7.10*10^{-3}M[/tex] ; &

solubility product of the given ionic solid is  [tex]1.5*10^{-14}[/tex]

  [tex]K_{sp}[/tex] [tex]= [Ag^+]^{2}[SO^{2-}_3][/tex]

[tex]1.5*10^{-14}[/tex] [tex]= (7.10*10^{-3})^2[/tex]  [tex][SO^{2-}_3][/tex]

[tex][SO^{2-}_3][/tex] = [tex]\frac{1.5*10^{-14}}{ (7.10*10^{-3})^2}[/tex]

          = 2.97560008 × 10⁻¹⁰

          ≅ [tex]2.96*10^{-10}M[/tex]

Thus, the concentration of [tex][SO^{2-}_3][/tex] is [tex]2.96*10^{-10}M[/tex]