1 Calculate the change in entropy that occurs in the system when 1.00 mol of methanol (CH3OH) vaporizes from a liquid to a gas at its boiling point (64.6 °C). For methanol, ΔHvap=35.21 kJ/mol.

Respuesta :

Answer: The change in entropy for the system is 140.3 J/K

Explanation:

The chemical equation follows:

[tex]CH_3OH(l)\rightleftharpoons CH_3OH(g)[/tex]

To calculate the entropy change for vaporization of methanol, we use the equation:

[tex]\Delta S=\frac{n\Delta H_{vap}}{T}[/tex]

where,

[tex]\Delta S[/tex] = entropy change of the reaction

n = number of moles = 1.00 mole

[tex]\Delta H_{vap}[/tex] = heat of vaporization = 35.21 kJ/mol = 35210 J/mol    (Conversion factor:  1 kJ = 1000 J)

T = temperature of the system = [tex]64.6^oC=[64.6+273]=337.6K[/tex]

Putting values in above equation, we get:

[tex]\Delta S=\frac{1.00mol\times 35210J/mol}{337.6K}\\\\\Delta S=140.3J/K[/tex]

Hence, the change in entropy for the system is 140.3 J/K

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