Gaseous compound Q contains only xenon and oxygen. When 0.100 gg of Q is placed in a 50.0 mLmL steel vessel at 0 ∘C∘C, the pressure is 0.229 atm

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Gaseous compound Q contains only xenon and oxygen. When a 0.100 g sample of Q is placed in a 50.0-mL steel vessel at 0°C, the pressure is 0.229 atm. What is the likely formula of the compound?

A. XeO

B. [tex]XeO_4[/tex]

C. [tex]Xe_2O_2[/tex]  

D. [tex]Xe_2O_3[/tex]

E. [tex]Xe_3O_2[/tex]

Answer: The chemical formula of the compound is [tex]XeO_4[/tex]

Explanation:

To calculate the molecular mass of the compound, we use the equation given by ideal gas equation:

PV = nRT

Or,

[tex]PV=\frac{w}{M}RT[/tex]

where,

P = Pressure of the gas = 0.229 atm

V = Volume of the gas  = 50.0 mL = 0.050 L     (Conversion factor:  1 L = 1000 mL)

w = Weight of the gas = 0.100 g

M = Molar mass of gas  = ?

R = Gas constant = [tex]0.0821\text{ L atm }mol^{-1}K^{-1}[/tex]

T = Temperature of the gas = [tex]0^oC=273K[/tex]

Putting value in above equation, we get:

[tex]0.229\times 0.050=\frac{0.100}{M}\times 0.0821\times 273\\\\M=\frac{0.100\times 0.0821\times 273}{0.229\times 0.050}=195.4g/mol\approx 195g/mol[/tex]

The compound having mass as 195 g/mol is [tex]XeO_4[/tex]

Hence, the chemical formula of the compound is [tex]XeO_4[/tex]

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