Consider the following standard reduction potentials in acid solution: The weakest reducing agent listed above is Co Cr Cr3 Mn2 MnO4-

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Consider the following standard reduction potentials in acid solution:

[tex]Cr^{3+}+3e^-\rightarrow Cr[/tex]      [tex]E^o=-0.74V[/tex]

[tex]Co^{2+}+2e^-\rightarrow Co[/tex]    [tex]E^o=-0.28V[/tex]

[tex]MnO_4^-+8H^++5e^-\rightarrow Mn^{2+}+4H_2O[/tex]    [tex]E^o=+1.51V[/tex]

The weakest reducing agent listed above is:

(a) [tex]Cr^{3+}[/tex]  

(b) [tex]Cr[/tex]  

(c) [tex]Mn^{2+}[/tex]

(d) [tex]MnO_4^-[/tex]

Answer : The correct option is, (d) [tex]MnO_4^-[/tex]

Explanation :

As we know that,

The substance having highest positive [tex]E^o[/tex] potential will always get reduced and will undergo reduction reaction and weakest reducing agent or strongest oxidizing agent.

From the standard reduction potentials we conclude that,

[tex]MnO_4^-[/tex] having highest positive [tex]E^o[/tex] potential than the other. So, it will always get reduced and will undergo reduction reaction and weakest reducing agent.

Hence, the correct option is, (d) [tex]MnO_4^-[/tex]

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