Answer:
[tex]\large \boxed{\text{77.4 mL}}[/tex]
Explanation:
Ba(OH)₂ + 2HCl ⟶ BaCl₂ + H₂O
V/mL: 249
c/mol·L⁻¹: 0.0443 0.285
1. Calculate the moles of Ba(OH)₂
[tex]\text{Moles of Ba(OH)$_{2}$} = \text{0.249 L Ba(OH)}_{2} \times \dfrac{\text{0.0443 mol Ba(OH)}_{2}}{\text{1 L Ba(OH)$_{2}$}} = \text{0.011 03 mol Ba(OH)}_{2}[/tex]
2. Calculate the moles of HCl
The molar ratio is 2 mol HCl:1 mol Ba(OH)₂
[tex]\text{Moles of HCl} = \text{0.011 03 mol Ba(OH)}_{2} \times \dfrac{\text{2 mol HCl}}{\text{1 mol Ba(OH)}_{2}} = \text{0.022 06 mol HCl}[/tex]
3. Calculate the volume of HCl
[tex]V_{\text{HCl}} = \text{0.022 06 mol HCl} \times \dfrac{\text{1 L HCl}}{\text{0.285 mol HCl}} = \text{0.0774 L HCl} = \textbf{77.4 mL HCl}\\\\\text{You must add $\large \boxed{\textbf{77.4 mL}}$ of HCl.}[/tex]