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The more salt in the water, the lower the freezing point will be. When freshwaterfreezeswater molecules of hydrogen and oxygen have bonded together into a crystalline structure of ice. The presence of salt makes it harder for water molecules to bond to the ice structure, because ice naturally repels salt molecules.
When you add salt to water, you lower to freezing point of the substance.

So for example, normal water freezes at 0°C. But water with salt in it won't freeze at 0°C, because its freezing point is lowered. 

In answer to the question. It takes longer for water with salt in it to freeze because the substance requires a lower temperature than normal water to freeze.
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